If your device has a RS232 plug, and there is some documentation, it is most likely that you can patch a driver for it within vvvv.
For some basics about the RS232 protocol, check the following articles:
Even if there is no documentation it is quite possible to reverse engineer serial protocols by using a second computer with two serial ports:
You now may either opt to emulate your driver or your device. the first is what you asked for, the latter may be fun as well.
There are also sophisticated programs available which allow you to intercept all data flowing between your device and an application, so you can avoid setting up a second computer. i remember being happy with the SerMon program from HHD Software.http://www.hhdsoftware.com/sermon.html Note there is a free trial version.
you may shorten Pins 2 and 3 of your 9-pole D-Sub connector.
any string you send using RS232 (Devices) should be answered now to its output.
Microsoft also provides a free tool from Sysinternals:http://www.microsoft.com/technet/sysinternals/utilities/portmon.mspx
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